Correct answer Carries: 4.
Wrong Answer Carries: -1.
A solution contains 6 g of a solute (molar mass = 120 g/mol) in 300 mL of solution. What is the molarity?
Moles of solute = \( \frac{6}{120} = 0.05 \, \text{mol} \).
Volume = 300 mL = 0.3 L.
Molarity = \( \frac{0.05}{0.3} \approx 0.1667 \, \text{M} \).
What is the volume of water required to prepare 200 mL of a 0.5 M solution using 4 g of NaOH (molar mass = 40 g/mol)?
Moles of NaOH = \( \frac{4}{40} = 0.1 \, \text{mol} \).
Molarity = \( \frac{\text{Moles}}{\text{Volume in L}} \), so \( 0.5 = \frac{0.1}{V} \).
Volume = \( \frac{0.1}{0.5} = 0.2 \, \text{L} = 200 \, \text{mL} \).
Since total volume is 200 mL, water volume = 200 mL (assuming solute volume is negligible).
What is the osmotic pressure of a 0.015 M solution of a non-electrolyte at 27°C? (\( R = 0.0821 \, \text{L atm mol}^{-1} \text{K}^{-1} \))
\( \Pi = MRT \).
\( \Pi = 0.015 \times 0.0821 \times 300 \approx 0.3695 \, \text{atm} \).
What is the mole fraction of a solute if the vapor pressure of a solution is 22 mm Hg and that of pure solvent is 25 mm Hg?
\( \frac{p^0 - p}{p^0} = x_{\text{solute}} \).
\( \frac{25 - 22}{25} = \frac{3}{25} = 0.12 \).
A solution contains 30 g of a solute in 120 g of water. If the mass percentage of the solute is increased to 25% by evaporating water, what mass of water remains?
Initial mass % = \( \frac{30}{30 + 120} \times 100 = 20\% \).
New mass % = \( 25\% = \frac{30}{30 + w} \times 100 \).
\( 0.25 (30 + w) = 30 \), \( 30 + w = 120 \), \( w = 90 \, \text{g} \).
A gas has a Henry’s law constant of 400 bar. If its partial pressure is 8 bar, what is the mole fraction in the solution?
\( p = K_H \cdot x \).
\( x = \frac{8}{400} = 0.02 \).
What is the mass of water required to prepare 300 g of a 5% by mass solution of a solute?
Mass of solute = \( \frac{5}{100} \times 300 = 15 \, \text{g} \).
Mass of water = \( 300 - 15 = 285 \, \text{g} \).
A 0.2 M solution of Na₂CO₃ (assuming complete dissociation) has an osmotic pressure of 1.968 atm at a certain temperature. What is the temperature? (\( R = 0.0821 \, \text{L atm mol}^{-1} \text{K}^{-1} \))
For Na₂CO₃, \( i = 3 \) (2Na⁺ + CO₃²⁻).
\( \Pi = i \cdot M \cdot RT \).
\( 1.968 = 3 \times 0.2 \times 0.0821 \times T \).
\( T = \frac{1.968}{0.6 \times 0.0821} \approx 40 \, \text{K} \).
What is the mass of urea (molar mass = 60 g/mol) required to prepare 2 kg of a 0.5 molal aqueous solution?
Molality = \( \frac{\text{Moles of solute}}{\text{Mass of solvent in kg}} \).
Moles = \( 0.5 \times 2 = 1 \, \text{mol} \).
Mass = \( 1 \times 60 = 60 \, \text{g} \).
A gas has a Henry’s law constant of 120 bar. If its mole fraction in a solution is 0.025, what is its partial pressure?
Henry’s law: \( p = K_H \cdot x \).
\( p = 120 \times 0.025 = 3 \, \text{bar} \).
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